Spectroscopic investigation of the interaction of methyldichlorosilane with organic solvents

Conclusions The interaction of methyldichlorosilane with organic solvents occurs on account of dipole-dipole interaction (halohydrocarbons), the formation of a SiH ... solvent hydrogen bond with the appearance of a or -complex presumably with a 1:1 composition (cyclohexane, benzene, nitrobenzene, benzonitrile, anisole, cyclohexanone, ethyl acetate, acetone, nitromethane, acetonitrile), and the formation of a SiH ... O hydrogen bond with coordination of a heteroatom of the solvent by the silicon atom and the appearance of a 1:2 complex (diethyl ether).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2473–2479, November, 1973.