Transformed steroids. 114. Direction of opening oxide ring of 16,17α-epoxy-17β-phenylandrost-4-en-3-one |
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| Authors: | A V Kamernitskii A V Skorova V V Isakov |
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| Institution: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions Starting with androst-5-en-3 -ol-17-one, we synthesized 16,17 -epoxy-17-phenylandrost-4-en-3-one. Cleavage of 17-C-O bond, adjacent to the phenyl ring, occurs during its nucleophilic opening, accompanied by 1,2-migration of the angular 18-CH3 group.See 1] for Communication 113.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1889–1893, August, 1980. |
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