Application of capillary electrophoresis to the uranyl/citrate system in moderately acidic solutions |
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Authors: | S Boughammoura J M’halla B Fourest |
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Institution: | (1) Laboratoire d’Electrochimie des solutions, Faculté des sciences, 5000 Monastir, Tunisia;(2) Institut de Physique Nucléaire, IN2P3-CNRS, Orsay Cedex, F-91406, France;(3) Univ. Paris-Sud, Orsay Cedex, F-91405, France |
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Abstract: | The capillary electrophoresis method has been applied to the speciation study of uranium(VI) at room temperature, in 0.02M
citrate buffer solutions, at pH values between 2.5 and 5.5 and at citrate/U ratios between 20 and 40. No negatively charged
species have been pointed out at pH values lower than 3. For a pH value higher than 5, the electropherograms are ill-defined
and the signals cannot be analyzed simply (owing to a high and rough baseline). In the pH range 3–5, up to 4 peaks can be
attributed to U(VI) species. Two of them are likely due to the expected monomer (UO2)(Cit)]−and dimer (UO2)2(Cit)2]2− complex species and these species are shown to be in quasi-equilibrium with two other species possessing slightly lower migration
velocities, (UO2)H(Cit)(OH)]− and (UO2)2H2(Cit)2(OH)2]2−, respectively. Speciation diagrams calculated by an exact analytical approach are proposed in order to explain the experimental
results. A complete agreement between theoretical and experimental results needs to take into account kinetic and hydrolysis
effects. |
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