| KINETICS OF ION TRANSFER ACROSS LIQUID/LIQUID INTERFACE BY CHRONOPOTENTIOMETRY WITH LINEAR CURRENT SCANNING |
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| 作者姓名： | 庞志诚 汪尔康 张正 |
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| 作者单位： | Laboratory of Electroanalytical Chemistry，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，PRC，Laboratory of Electroanalytical Chemistry，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，PRC，University of Texas at E1 Paso，U. S. A.，Laboratory of Electroanalytical Chemistry，Changchun Institute of Applied Chemistry，Academia Sinica，Changchun 130022，PRC，University of Texas at E1 Paso，U. S. A |
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| 基金项目： | Project supported by the National Natural Science Foundation of China. |
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| 摘 要： | The equation of the potential-current curve for the ion transfer across the liquid/liquid interface during the linear current scanning has been derived theoretically. A method to calculate the kinetics parameters for the ion transfer by the way of linear current scanning is presented. The transfer of TPAs~+ ions, which is a typical basic electrolyte ion usually used in liquld/liquid interface electrochemistry, was practically investigated at the water/nitrobenzene interface.
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KINETICS OF ION TRANSFER ACROSS LIQUID/LIQUID INTERFACE BY CHRONOPOTENTIOMETRY WITH LINEAR CURRENT SCANNING |
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| PANG ZHI-CHENG WANG ER-KANG AND ZHANG ZHENG.KINETICS OF ION TRANSFER ACROSS LIQUID/LIQUID INTERFACE BY CHRONOPOTENTIOMETRY WITH LINEAR CURRENT SCANNING[J].Science in China(Chemistry),1990(10). |
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| Authors: | PANG ZHI-CHENG WANG ER-KANG AND ZHANG ZHENG |
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| Abstract: | The equation of the potential-current curve for the ion transfer across the liquid/liquid interface during the linear current scanning has been derived theoretically. A method to calculate the kinetics parameters for the ion transfer by the way of linear current scanning is presented. The transfer of TPAs~+ ions, which is a typical basic electrolyte ion usually used in liquld/liquid interface electrochemistry, was practically investigated at the water/nitrobenzene interface. |
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| Keywords: | liquid/liquid interface linear current scanning ion transfer kinetics |
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