Carrier energy spectrum and lifetime in quantum dots in electric field

The S-matrix formalism is used to perform analytical calculations of the spectrum of quasi-stationary states of charge carriers in a core-shell quantum dot. Analytical expressions are obtained for the second-order perturbative corrections to the position and half-width of a quasi-stationary energy level, and level shifts are calculated numerically for a core-shell quantum dot in the presence of an electrostatic field. The corrections to level half-width due to Stark effect are analyzed as functions of level energy and barrier thickness. It is shown that there exists a level position E _cr such that the correction δΓ to the level half-width changes sign. An analytical expression for the quadratic Stark shift in a dc-biased quantum well is found in semiclassical approximation. It is shown that the corresponding correction δΓ to half-width also changes sign as energy passes through E _cr. As an example, the Stark shift is calculated for a core-shell quantum dot in the electrostatic field of an adjacent protein molecule.