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Chirality of silver nanoparticles synthesized on DNA
Authors:Shemer Gabriel  Krichevski Olga  Markovich Gil  Molotsky Tatiana  Lubitz Irit  Kotlyar Alexander B
Institution:School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences and Department of Biochemistry, George S. Wise Faculty of Life Sciences, Tel Aviv University, Tel Aviv, 69978, Israel.
Abstract:Silver nanocrystals grown on a poly(dG)-poly(dC) double stranded DNA scaffold displayed circular dichroism at their surface plasmon excitation band. This chiral plasmon signature was not observed in a control experiment where silver nanocrystals of similar size were produced without the DNA template and adsorbed to the DNA. It is concluded that the DNA templated Ag nanocrystals had a preferred structural handedness.
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