甲基丙烯酸烷基磺酸钠在嵌段聚醚氨酯膜上接枝聚合的研究

本文对两种新合成的亲水性单体,甲基丙烯酸已磺酸钠和甲基丙烯酸辛磺酸钠在聚醚氨酯膜上接枝聚合进行了研究。其反应分两步:首先,在过氧化氢存在下,将膜进行光氧化,引入过氧化氢基团;然后,在还原剂亚铁盐作用下,引发甲基丙烯酸烷基磺酸酯接枝聚合。单体浓度、亚铁盐浓度、反应温度对接枝速率均有影响。接枝膜与基膜相比,吸水率与抗凝血性能均有提高。辛酯接枝膜的抗凝血性能显得更好。用扫描电镜可观察到膜上接枝物的图象。

STUDIES ON GRAFT POLYMERIZATION OF SULFOALKYL METHACRYLATE ONTO SEGMENTED POLYETHER URETHANE FILM

Graft polymerization of sodium salt of 6-sulfohexyl methacrylate (SSHMA) or sodium salt of 8-sulfo-octyl methacrylate (SSOMA) onto segmented polyether urethane (SPEU) film was investigated.Graft reaction included two steps: f irst,hydroperoxide group was introduced onto the surface of SPEU through photo-oxidation in the presence of hydrogen peroxide, then it was reduced by ferrous ion to initiate sulfoalkyl methacrylate grafting on SPEU surface. The effect of the concentration of sulfoalkyl methacrylate, the concentration of ferrous ion and reaction temperature on the graft polymerization was discussed. The grafted films posses higher percentage of water absorption and anticoagulant activity than the ungrafted SPEU film. The salient micrographs on surface of grafted film were taken by scanning electronic microscope.