Synthesis of 1,4,5,6-tetrahydropyridine derivatives starting from trans-3-chloro-1,3-alkadien-5-ones |
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Authors: | G G Melikyan K A Atanesyan G Kh Aslanyan M R Tirakyan L A Khachatryan Sh O Badanyan |
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Institution: | (1) Institute of Organic Chemistry, Academy of Sciences of the Armenian SSR, 375094 Erevan |
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Abstract: | A method has been developed for the synthesis of 3-carbethoxy-2-methyl-6-(oxoalkylidene)-1,4,5,6-tetrahydropyridines by reaction of trans-3-chloro-1,3-alkadien-5-ones with ethyl aminocrotonate. It is shown that the corresponding vinylacetylanic ketones are intermediate products of the reactions.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 497–500, April, 1987. |
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