NaOH-catalyzed crossed Claisen condensation between ketene silyl acetals and methyl esters |
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| Authors: | Iida Akira Takai Kenta Okabayashi Tomohito Misaki Tomonori Tanabe Yoo |
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| Affiliation: | Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, Hyogo, Japan. |
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| Abstract: | We have developed a practical crossed Claisen condensation between ketene silyl acetals and methyl esters using catalytic NaOH to obtain alpha-monoalkylated beta-keto esters and inaccessible alpha,alpha-dialkylated beta-keto esters. |
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