Insertion of acetylene into osmium-hydrogen bonds incluster complexes |
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| Authors: | A J Deeming S Hasso M Underhill |
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| Institution: | Department of Chemistry, University College London, 20 Gordon Street, London WC1H OAJ Great Britain |
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| Abstract: | Complex H2 Os3 (CO)10 reacts with acetylene or methyl-substituted acetylenes to give complexes of type HOs3 (CH=CHR)(CO)10 (R = H or Me) and Os3 (R1 C2 R2)(CO)10 (R1 and R2 are H or Me) which convert to nonacarbonyl complexes with hydrogen transfer from ligand to metal. |
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