The cation as a tool to get spin-canted three-dimensional ironIII networks |
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| Authors: | Armentano Donatella De Munno Giovanni Mastropietro Teresa F Proserpio Davide M Julve Miguel Lloret Francesc |
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| Institution: | Dipartimento di Chimica, Università degli Studi della Calabria, 87030 Arcavacata di Rende, Cosenza, Italy. |
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| Abstract: | Alkyl-substituted ammonium cations (X) allow the preparation of a series of spin-canted oxo- and oxalato-bridged three-dimensional iron(III) networks, exhibiting magnetic ordering at T(c) values ranging from 40 to 56 K. The value of T(c) varies with the cation despite the lack of significant structural modifications. |
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