Calorimetric investigations of luminescent films polycarbonate (PC) doped with europium complex [Eu(TTA)3(H2O)2] |
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| Authors: | Pedro Lima Forster Ademar Benevolo Lugao Hermi Felinto Brito Duclerc Fernandes Parra |
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| Affiliation: | 1.Chemistry and Environmental Centre, Institute of Energetics and Nuclear Researches,National Commission of Nuclear Energy, IPEN/CNEN-SP,S?o Paulo,Brazil;2.Department of Fundamental Chemistry, Chemistry Institute,University of S?o Paulo,S?o Paulo,Brazil |
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| Abstract: | Polymers doped with rare earth complexes are advantaged in film production for many applications in the luminescent field. In this luminescent polycarbonate (PC) films doped with diaquatris(thenoyltrifluoroacetonate)europium(III) complex [Eu(TTA)3(H2O)2] were prepared and their calorimetric and luminescent properties in the solid state are reported. The thermal behavior was investigated by utilization of differential scanning calorimetry (DSC) and thermogravimetry (TG). Due of the addition of rare earth [Eu(TTA)3(H2O)2] into PC matrix, changes were observed in the thermal behavior concerning the glass transition and thermal stability. Characteristic broadened narrow bands arising from the 5D0 → 7FJ transitions (J = 4−0) of Eu3+ ion indicate the incorporation of the Eu3+ ions in the polymer. The luminescent films show enhancement emission intensity with an increase of rare earth concentration in polymeric matrix accompanied by decrease in thermal stability. |
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