Aldol- and Mannich-type reactions via in situ olefin migration in ionic liquid |
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| Authors: | Yang Xiao-Fan Wang Mingwen Varma Rajender S Li Chao-Jun |
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| Institution: | Department of Chemistry, Tulane University, New Orleans, Louisiana 70118, USA. |
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| Abstract: | An aldol-type and a Mannich-type reaction via the cross-coupling of aldehydes and imines with allylic alcohols catalyzed by RuCl(2)(PPh(3))(3) was developed with ionic liquid as the solvent. The solvent/catalyst system could be reused for at least five times with no loss of reactivity. |
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