First synthesis of perfluorinated corrole and its mn=o complex |
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| Authors: | Liu Hai-Yang Lai Tat-Shing Yeung Lam-Lung Chang Chi K |
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| Institution: | Department of Chemistry, Lab of Chemical Biology, Inst. of Molecular Technology for Drug Discovery and Synthesis, Hong Kong Univ. of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China. |
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| Abstract: | A novel perfluorinated corrole, 2,3,7,8,12,13,17,18-octafluoro-5,10,15-tris(pentafluorophenyl)corrole, and its manganese(III) and oxomanganese(V) derivatives have been synthesized. The perfluorinated manganese corrolate exhibited excellent reactivity and stability in the catalytic oxidation of alkenes with iodosylbenzene. |
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