Redox inversion of helicity in propeller-shaped molecules derived from s-methyl cysteine and methioninol |
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| Authors: | Barcena Homar S Holmes Andrea E Zahn Steffen Canary James W |
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| Affiliation: | Department of Chemistry, New York University, New York, New York 10003, USA. |
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| Abstract: | One-electron reduction inverts the helicity of copper complexes formed from derivatives of S-methylcysteine and methioninol. The change in conformation of the organic ligand is followed in the exciton-coupled circular dichroism (ECCD) spectra of the complexes. |
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