Electronic and infrared spectral studies of manganese(III) selenito complexes |
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Authors: | Bishan L Khandelwal Siva P Mallela |
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Institution: | (1) Department of Chemistry, Indian Institute of Technology, 110016 New Delhi, India |
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Abstract: | Summary Selenito manganese(III) complexes of the type MMn(SeO3)2 · × H2O (where M = H+, NH
4
+
, K+, Rb+ and Cs+) have been prepared, Magnetic measurements show all these complexes to be of high spin d4 type, On the basis of their i.r. and electronic spectral studies and other properties, a polymeric octahedral structure involving bridging oxygen atoms has been suggested. |
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