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Oxide talum-containing catalysts of ozone decomposition and methane oxidation
Authors:S. N. Tkachenko  G. V. Egorova  L. A. Zaloznaya  A. V. Fionov  V. A. Voblikova  L. V. Sabitova  A. N. Kharlanov  G. P. Murav’eva  I. S. Tkachenko  V. V. Lunin
Affiliation:1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia
Abstract:The oxidation of manganese ions is shown to occur in ozone decomposition on manganese-containing catalyst, leading to the deactivation of a sample. The structure of the iron-containing catalyst does not change, ensuring its high stability during ozone decomposition in a dry gas flow at room temperature, conducted in the region of inner diffusion with an activation energy of 15.5 ± 0.7 kJ/mol. The presence of manganese cations in the intermediate stages of reduction is found to increase their activity in the reaction of deep methane oxidation.
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