Oxide talum-containing catalysts of ozone decomposition and methane oxidation |
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Authors: | S. N. Tkachenko G. V. Egorova L. A. Zaloznaya A. V. Fionov V. A. Voblikova L. V. Sabitova A. N. Kharlanov G. P. Murav’eva I. S. Tkachenko V. V. Lunin |
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Affiliation: | 1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia
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Abstract: | The oxidation of manganese ions is shown to occur in ozone decomposition on manganese-containing catalyst, leading to the deactivation of a sample. The structure of the iron-containing catalyst does not change, ensuring its high stability during ozone decomposition in a dry gas flow at room temperature, conducted in the region of inner diffusion with an activation energy of 15.5 ± 0.7 kJ/mol. The presence of manganese cations in the intermediate stages of reduction is found to increase their activity in the reaction of deep methane oxidation. |
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