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Determination of engineered nanoparticles on textiles and in textile wastewaters
Authors:Iva Rezi?
Affiliation:Laboratory of Analytical Chemistry, Department of Applied Chemistry, Faculty of Textile Technology, University of Zagreb, Prilaz Baruna Filipovi?a 28a, 10000 Zagreb, Croatia
Abstract:Textile materials with engineered nanoparticles (ENPs) have excellent properties as they are antibacterial, antimicrobial, water resistant and protective. The textile industry has recognized the importance and the advantages of ENPs, so they comprise one of the fastest developing branches of processing.The most important sources of ENPs released to the environment from textiles are textile-industry wastewaters and waters from large hospital or hotel laundries. In addition, waste textile materials coated with ENPs present a threat to the environment, if such materials are not properly handled and disposed of after use.Currently, the toxicity and the potential harm of ENPs widely applied on textiles are not thoroughly investigated and/or eliminated. Consequently, there is an urgent need to define the most appropriate analytical methods for monitoring ENPs on textiles.This review presents the most important techniques for monitoring ENPs on textile materials and in textile-wastewater samples, from the perspective of protecting the environment and human health.
Keywords:AgNP, Silver nanoparticle   AS, Acoustic spectroscopy   AEM, Analytical electron microscopy   AF4, Asymmetric flow field-flow fractionation   APPI-MS, Atmospheric pressure photo ionization-mass spectrometry   AFM, Atomic force microscopy   CE, Capillary electrophoresis   CLSM, Confocal laser scanning microscopy   CFF, Cross-flow filtration   DLS, Dynamic light scattering   EM, Electron microscopy   EDS, Energy dispersive X-ray spectroscopy   ENP, Engineered nanoparticle   ESEM, Environmental scanning electron microscopy   FFF, Field-flow fractionation   FAAS, Flame atomic absorption spectrometry   GF-AAS, Graphite furnace atomic absorption spectrometry   HPLC, High-performance liquid chromatography   HDC, Hydrodynamic chromatography   IR, Infrared spectroscopy   ICP-MS, Inductively coupled plasma mass spectrometry   ICP-OES, Inductively coupled plasma-optical emission spectrometry   IEC, Ion-exchange chromatography   LA-ICP-MS, Laser ablation ICP-MS   LDI-TOF-MS, Laser desorption/ionization time-of-flight-mass spectrometry   LDV, Laser Doppler velocimetry   LC, Liquid chromatography   MALDI-TOF-MS, Matrix-assisted laser desorption/ionization-time-of-flight-mass spectrometry   MAE, Microwave-assisted extraction   MALLS, Multi-angle laser light scattering   NP, Nanoparticle   NTA, Nanoparticle-tracking analysis   NMR, Nuclear magnetic resonance spectroscopy   PCS, Photon correlation spectroscopy   RS, Raman spectroscopy   SWEM, Scanning electron microscopy   SIMS, Secondary ion mass spectroscopy   SEC, Size-exclusion chromatography   SPE, Solid-phase extraction, SLS, Static light scattering   TEM, Transmission electron microscopy   UAE, Ultrasonic-assisted extraction   UV-VIS, Ultraviolet-visible spectroscopy   XPS, X-ray photoelectron spectrometry
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