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Determination of engineered nanoparticles on textiles and in textile wastewaters
Authors:Iva Rezi?
Institution:Laboratory of Analytical Chemistry, Department of Applied Chemistry, Faculty of Textile Technology, University of Zagreb, Prilaz Baruna Filipovi?a 28a, 10000 Zagreb, Croatia
Abstract:Textile materials with engineered nanoparticles (ENPs) have excellent properties as they are antibacterial, antimicrobial, water resistant and protective. The textile industry has recognized the importance and the advantages of ENPs, so they comprise one of the fastest developing branches of processing.The most important sources of ENPs released to the environment from textiles are textile-industry wastewaters and waters from large hospital or hotel laundries. In addition, waste textile materials coated with ENPs present a threat to the environment, if such materials are not properly handled and disposed of after use.Currently, the toxicity and the potential harm of ENPs widely applied on textiles are not thoroughly investigated and/or eliminated. Consequently, there is an urgent need to define the most appropriate analytical methods for monitoring ENPs on textiles.This review presents the most important techniques for monitoring ENPs on textile materials and in textile-wastewater samples, from the perspective of protecting the environment and human health.
Keywords:AgNP  Silver nanoparticle  AS  Acoustic spectroscopy  AEM  Analytical electron microscopy  AF4  Asymmetric flow field-flow fractionation  APPI-MS  Atmospheric pressure photo ionization-mass spectrometry  AFM  Atomic force microscopy  CE  Capillary electrophoresis  CLSM  Confocal laser scanning microscopy  CFF  Cross-flow filtration  DLS  Dynamic light scattering  EM  Electron microscopy  EDS  Energy dispersive X-ray spectroscopy  ENP  Engineered nanoparticle  ESEM  Environmental scanning electron microscopy  FFF  Field-flow fractionation  FAAS  Flame atomic absorption spectrometry  GF-AAS  Graphite furnace atomic absorption spectrometry  HPLC  High-performance liquid chromatography  HDC  Hydrodynamic chromatography  IR  Infrared spectroscopy  ICP-MS  Inductively coupled plasma mass spectrometry  ICP-OES  Inductively coupled plasma-optical emission spectrometry  IEC  Ion-exchange chromatography  LA-ICP-MS  Laser ablation ICP-MS  LDI-TOF-MS  Laser desorption/ionization time-of-flight-mass spectrometry  LDV  Laser Doppler velocimetry  LC  Liquid chromatography  MALDI-TOF-MS  Matrix-assisted laser desorption/ionization-time-of-flight-mass spectrometry  MAE  Microwave-assisted extraction  MALLS  Multi-angle laser light scattering  NP  Nanoparticle  NTA  Nanoparticle-tracking analysis  NMR  Nuclear magnetic resonance spectroscopy  PCS  Photon correlation spectroscopy  RS  Raman spectroscopy  SWEM  Scanning electron microscopy  SIMS  Secondary ion mass spectroscopy  SEC  Size-exclusion chromatography  SPE  Solid-phase extraction  SLS  Static light scattering  TEM  Transmission electron microscopy  UAE  Ultrasonic-assisted extraction  UV-VIS  Ultraviolet-visible spectroscopy  XPS  X-ray photoelectron spectrometry
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