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Studies with arylhydrazonopyridinones: Synthesis of new arylhydrazono thieno[3,4-c]pyridinones as novel D2T2 dye class; classical verse green methodologies
Authors:Khadijah M Al-Zaydi  Rita M Borik  Mohamed H Elnagdi
Institution:1. Department of Chemistry, Girl’s College of Education, Jeddah, P.O. Box 50918, Jeddah 21533, Saudi Arabia;2. Department of Chemistry, Faculty of Science, University of Kuwait, P.O. Box 5969, Safat, 13060 Kuwait, Saudi Arabia
Abstract:A variety of arylhydrazonopyridinones were prepared via heating cyanoacetamides with ethyl acetoacetate in absence of solvent under reflux conventionally or ultrasound irradiation or in a microwave oven. The formed products 5 and 6 could be readily converted to thienopyridones. Attempted addition of the latter to electron poor olefins afforded only arylhydrazonopyridinones.
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