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Effect of sintering temperature and thermoelectric power studies of the system MgFe2−xCrxO4
Authors:PP Hankare  VT Vader  UB Sankpal  LV Gavali  R Sasikala  IS Mulla
Institution:1. Solid State Research Laboratory, Department of Chemistry, Shivaji University, Kolhapur 416 004, India;2. Chemistry Division, Bhabha Atomic Research Centre, Mumbai-411 008, India;3. National Chemical Laboratory, Pune-411 008, India
Abstract:Mixed metal oxides showing the spinel structure exhibit interesting structural and electrical properties. Substances with specific compositions in the system MgFe2?xCrxO4 were synthesized by the simple co-precipitation method and have been investigated by X-ray diffraction (XRD) and scanning electron microscope (SEM) to study the effect of temperature on the size of particles and grains. The infrared spectrum shows, two strong bands around 600 and 500 cm?1. An elemental composition of one of the samples, MgFeCrO4 was found by energy dispersive X-ray spectroscopy (EDS). The thermoelectric power measurements carried out from room temperature to 500 °C, show both n-type and p-type behavior.
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