Potentiometric titration of plutonium |
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Authors: | G L Silver |
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Institution: | (1) Mound Laboratory, Monsanto Research Corporation, 45342 Miamisburg, Ohio, (USA) |
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Abstract: | In the potentiometric titration of plutonium(III), it has been customary to take the equivalence point as the inflection point
on a plot of potential vs. volume of titrant.1 That the stoichiometric end point corresponds to the inflection point does not seem to have been theoretically demonstrated,
however. The purpose of this letter is to suggest that these points may not correspond in the potentiometric titration of
plutonium(III).
Mound Laboratory is operated by Monsanto Research Corporation for USERDA under contract No. EY-76-C-04-0053. |
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