| Heck Reaction of Iodoarenes with Methyl Acrylate Catalyzed by Cyciopalladated Complexes of Tertiary Arylamines Immobilized in Ionic Liquid[ Bmim ] ^＋ BF4^- |
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| 引用本文： | 郑瑞,杨帆,邹刚,汤杰,何鸣元.Heck Reaction of Iodoarenes with Methyl Acrylate Catalyzed by Cyciopalladated Complexes of Tertiary Arylamines Immobilized in Ionic Liquid[ Bmim ] ^＋ BF4^-[J].中国化学,2003,21(9):1111-1113. |
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| 作者姓名： | 郑瑞 杨帆 邹刚 汤杰 何鸣元 |
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| 作者单位： | CenterfortheChemistryofIonicLiquids,DepartmentofChemistry,EastChinaNormalUniversity,Shanghai200062,China |
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| 摘 要： | Heck reaction of iodoarenes with methyl acrylate, catalyzed by cyclolmlladated complexes of tertiary arylamines, was investi-gated in ionic liquid 1-butyl-3-metylimidazolium tetratluorobo-rate (Bmim] BF4^- ). The products can be isolated convenient-ly from the ionic liquid-catalyst system. The catalysts could be reused for more than 10 times still with satisfactory catalytic ac-tivity.
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| 关 键 词： | Heck反应 甲基丙烯酸酯 催化反应 碘代芳烃 环钯配合物 芳胺 催化剂 |
Heck reaction of iodoarenes with methyl acrylate catalyzed by cyclopalladated complexes of tertiary arylamines immobilized in ionic liquid [Bmim]+BF4− |
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| Rui Zheng,Fan Yang,Gang Zou,Jie Tang,Ming‐Yuan He.Heck reaction of iodoarenes with methyl acrylate catalyzed by cyclopalladated complexes of tertiary arylamines immobilized in ionic liquid [Bmim]+BF4−[J].Chinese Journal of Chemistry,2003,21(9):1111-1113. |
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| Authors: | Rui Zheng Fan Yang Gang Zou Jie Tang Ming‐Yuan He |
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| Abstract: | Heck reaction of iodoarenes with methyl acrylate, catalyzed by cyclopalladated complexes of tertiary arylamines, was investigated in ionic liquid 1‐butyl‐3‐methy Imidazolium tetrafluoroborate (Bmim] +BF4?). The products can be isolated conveniently from the ionic liquid‐catalyst system. The catalysts could be reused for more than 10 times still with satisfactory catalytic activity. |
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| Keywords: | cyclopalladated complexes of tertiary arylamines ionic liquid Heck reaction |
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