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Immobilization of gold nanoparticles on poly(methyl methacrylate) electrospun fibers exhibiting solid‐state surface plasmon effect
Authors:Nguyen Dang Luong  Joonsuk Oh  Youngkwan Lee  Ji Hyun Yeon  Jaehuyn Hur  Jong Jin Park  Jong Min Kim  Jae‐Do Nam
Institution:1. Gyeonggi Regional Research Center, SKKU Advanced Institute of Nanotechnology, Sungkyunkwan University, Suwon, South Korea;2. Laboratory of Polymer Technology, Department of Biotechnology and Chemical Technology, Aalto University, School of Chemical Technology, P.O. Box 16100, 00076 Aalto, Finland;3. Department of Polymer Science and Engineering, Sungkyunkwan University, Suwon, South Korea;4. School of Chemistry, Sungkyunkwan University, Suwon, South Korea;5. Samsung Advanced Institute of Technology (SAIT), Suwon, South Korea
Abstract:In this study, the surface plasmon effect of Au nanoparticles was successfully realized in the solid state by embedding the Au nanoparticles on the surface of the transparent polymer fibers for the first time. Electrospinning a poly(methyl methacrylate) (PMMA) and HAuCl4 mixture followed by a wet chemical reduction, the gold nanoparticles were formed on the PMMA nanocomposite electrospun fibers in a well‐distributed manner to give photostable purple color. The Au nanoparticles were all sphere shaped with an average diameter of 12 nm. Specifically, simply adjusting HAuCl4 salt concentration in the electrospinning solution, it is able to control the electrospun fiber diameter and gold nanoparticle content in the resulting PMMA/Au nanocomposite fibers. Therefore, the developed method described herein is simple and effective for the large volume production of PMMA/Au nanocomposite fibers. Copyright © 2011 John Wiley & Sons, Ltd.
Keywords:gold nanoparticles  poly(methyl methacrylate)  electrospinning  surface plasmon
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