Interaction of dicyclopentadienyltitanium dichloride with bis(triethylgermyl)-cadmium and -mercury |
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| Authors: | GA Razuvaev VN Latyaeva LI Vishinskaya VT Bytchkov GA Vasilyeva |
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| Institution: | Institute of Chemistry, U.S.S.R. Academy of Sciences, Gorky U.S.S.R. |
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| Abstract: | The reaction of dicyclopentadienyltitanium dichloride with bis(triethylgermyl)mercury in benzene solution at 20° yields metallic mercury quantitatively, titanocene monochloride and triethylchlorogermane. The reaction of dicyclopentadienyltitanium dichloride with bis(triethylgermyl)cadmium leads to the formation of a complex of the following general composition: Cp2TiCl2 - Cd(GeEt3)2]. The reactivity of this complex has been studied: in toluene solution at 20° it decomposes slowly to yield metallic cadmium, triethylchlorogermane and Cp2TiCl(GeEt3). |
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| Keywords: | To whom Correspondence should be addressed |
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