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On the molecular structure and nmr spectrum of cis-[PtPh2(Ph2PCH2PPh2)]
Authors:Paul S Braterman  Ronald J Cross  Ljubica Manojlović-Muir  Kenneth W Muir  GBrent Young
Institution:Chemistry Department, The University, Glasgow G 12 8QQ Great Britain
Abstract:The X-ray crystal structure analysis of cis-PtPh2(Ph2PCH2PPh2)] suggests that the unusually low PtP coupling constant is a consequence of distortion of the valency angles at the platinum and phosphorus atoms; the restrictive geometry of the chelate ring does not effect the lengths of the metal—ligand bonds.
Keywords:To whom correspondence should be addressed  
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