Transaminierungen am dimethylamino-bis-(trifluormethyl)-arsin und -phosphin |
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| Authors: | O Adler F Kober |
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| Institution: | Eduard Zintl-Institut für Anorganische und Physikalische Chemie der Technischen Hochschule Darmstadt, Darmstadt Bundesrepublik Deutschland |
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| Abstract: | The arsines and phosphines (CF3)2EN(CH3)2 (E= P or As) react with secondary amines with the formation of (CF3)2ENR2 and HN(CH3)2. Mechanistic and steric effects associated with these reactions are discussed. The influence of the groups (CF3)2E on the E-N-bonding and the reaction is examined. |
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