Organometallic compounds having metal-metal bonds : XXIII. Hydrido(triphenylgermanium)tetracarbonyliron and its conjugate base |
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| Authors: | E.E. Isaacs W.A.G. Graham |
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| Affiliation: | Department of Chemistry, University of Alberta, Edmonton, Alberta T6G 2E1 Canada |
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| Abstract: | Reaction of Ph3GeLi with [Et4N][HFe3(CO)11] affords the new carbonylferrate salt [Et4N][Ph3GeFe(CO)4] and the same reaction provides an alternative route to the known silicon and tin analogs. Protonation of [Et4N][Ph3GeFe(CO)4] with HCl in ether-THF forms the air-sensitive, thermally rather unstable cis-Ph3GeFeH(CO)4. The latter protonates chloride ions in dichloromethane. |
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