Oxidation metallorganischer verbindungen : I. Zur oxidation isomerer diibutylaluminium-n-hexanolate |
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| Authors: | Günter Schmitt |
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| Institution: | Institut für Technische Chemie und Petrolchemie der Rheinisch-Westfälischen Technischen Hochschule Aachen D 5100 Aachen, Alte Maastrichter Str. 2 B.R.D. |
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| Abstract: | Oxidation of isomeric diisobutylaluminium-n-hexenolates with oxygen yields after subsequent acetolysis besides the expected hexenol acetates also hexanetriol triacetates. Their formation is explained by intramolecular epoxidation with alkylalkoxyaluminium peroxides formed during the oxidation. |
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