Mechanistic aspects of (CC) isomerization in vinylic rhodium(III) complexes |
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| Authors: | Donald W. Hart Jeffrey Schwartz |
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| Affiliation: | Department of Chemistry, Princeton University, Princeton, New Jersey 08540 U.S.A. |
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| Abstract: | Observations concerning the (CC) isomerization of several vinylic RhIII complexes suggest an intramolecular pathway; isomerization occurs at a rate which is affected by the backbonding ability of the metal and the π-acidity of the vinylic ligand in the complex. |
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| Keywords: | Author to whom correspondence should be addressed. |
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