The insertion of carbon oxysulfide into some organo-metallic amines |
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Authors: | W.S. Moore C.H. Yoder |
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Affiliation: | Department of Chemistry, Franklin and Marshall College, Lancaster, Pa. 17604 U.S.A. |
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Abstract: | The structures of the products obtained when carbon oxysulfide is allowed to react with organometallic amines of germanium, pholphorus, and arsenic are determined and the effect of changing hardness of the organo-metallic center is discussed. Free energies of activation for rotation about the carbonylnitrogen bond in the products are determined. |
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