Hydrogen Bonding Network of 4‐Amidiniumpyridine Acetate and PtIIbis(triphenylphosphine) Complexes with 4‐Amidinepyridine |
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| Authors: | Luca Rigamonti Stefano Carlino Carlo Castellano Prof Dr Francesco Demartin Prof Dr Alessandro Pasini |
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| Institution: | 1. Università degli Studi di Milano, Dipartimento di Chimica, Via Golgi 19, 20133 Milano, Italy;2. Università degli Studi di Firenze, Dipartimento di Chimica ‘U. Schiff', Via della Lastruccia 3–13, 50019 Sesto Fiorentino (FI), Italy |
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| Abstract: | The X‐ray structures of 4‐amidiniumpyridine acetate, ( 1· H)AcO, and of cis‐Pt( 1 )2(PPh3)2](NO3)2 ( 2 ), as well as their IR spectra, reveal intramolecular hydrogen bonding, which held together the cations and the anions. The IR spectroscopic data suggest that this may be so also in cis‐PtCl( 1 )(PPh3)2](BF4) ( 3 ). In ( 1· H)AcO and in 2 extensive intermolecular hydrogen bonding networks span through the whole crystals. |
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| Keywords: | 4‐Amidiniumpyridine Hydrogen bonds Crystal structure Platinum |
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