New Borate‐citrate: Synthesis,Structure, and Properties of Sr[B(C6H5O7)2](H2O)4·3H2O |
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| Authors: | Hongping Wu Dr Shilie Pan Dianzeng Jia Hongwei Yu Zhaohui Chen |
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| Institution: | 1. College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, P. R. China;2. Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, 40–1 South Beijing Road, Urumqi 830011, P. R. China |
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| Abstract: | Single crystals of SrB(C6H5O7)2](H2O)4 · 3H2O, a new borate‐citrate material, were grown with sizes up to 8 × 6 × 2 mm by slow evaporation of water at room temperature. The structure of SrB(C6H5O7)2](H2O)4 · 3H2O was determined by single‐crystal X‐ray diffraction. It crystallizes in the monoclinic space group P21/c, with a = 11.363(3) Å, b = 18.829(4) Å, c = 11.976(3) Å, β = 110.736(3)°, and Z = 4. The SrO8 dodecahedra, BO4 tetrahedra and citrate groups are linked together to form chains. The compound was characterized by IR and UV/Vis/NIR transmittance spectroscopy as well as thermal analysis. |
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| Keywords: | Sr[B(C6H5O7)2](H2O)4· 3H2O Single crystal growth X‐ray diffraction Optical properties |
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