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Some unexpected reactions of perfluoroalkynylmagnesium halides

Authors:	G Santini M Le Blanc JG Riess

Institution:	Laboratoire de Chimie Minérale Moléculaire, Equipe de Recherche Associée au C.N.R.S., Institut de Mathématiqués èt Sciences Physiques, Parc Valrose, 06034 Nice Cédex France

Abstract:	R_FCCMgX reacts with Ac₂O to give not only MeC(O)CCR_F but also MeC(O)CXC(R_F)C(O)Me, and with CF₃COOPr it gives CF₃C(O)CHC(OPr)R_F not CF₃C(O)CCR_F; R_FCCMgBr reacts with Cl₂ to give R_FCCBr rather than R_FCCCl, while with Br₂ R_FCCMgI similarly gives R_FCCI rather than R_FCCBr.

Keywords:	To whom correspondence should be addressed
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