A new synthesis of spirobenzylisoquinolines. Analogues of sibiricine and corydaine |
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Authors: | Herbert L Holland David B MacLean Russell GA Rodrigo Richard FH Manske |
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Institution: | Department of Chemistry, McMaster University Hamilton, Ontario, Canada;Department of Chemistry, The University of Waterloo Waterloo, Ontario, Canada |
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Abstract: | The reduction product of dehydrocordrastine, , with di-isobutylaluminum hydride spontaneously rearranged to the spirobenzylisoquinolines and , analogous to the alkaloids sibiricine (), corydaine (), and yenhusomidine (). |
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