Übergangsmetall-substituierte vb elementsysteme : VIII. Darstellung und komplexchemisches verhalten von cyclopentadienyl(tricarbonyl)viametall-dimethylstibinen |
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Authors: | Wolfgang Malisch Peter Panster |
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Institution: | Institute für Anorganische Chemie der Universität Würzburg, D 8700 Würzburg Am Hubland B.R.D. |
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Abstract: | Starting with the cyclopentadienyl(carbonyl)metal anions π-C5H5(CO)3M]? (M = Cr, Mo, W) and (CH3)2SbBr, transition metal-substituted stibines of the form π-C5H5(CO)3MSb(CH3)2 are obtained. The nucleophilic character of the VB element primarily determines the reactivity of these species, and shows itself in alkyl halide quarternization (a) or ligand exchange on activated metal carbonyl complexes (b). (a) yields the trialkylstibine-substituted metal cations π-C5H5-(CO)3MSb(CH3)2R]X (R = CH3, CH2CH=CH2, CH2C6H5; X = Br, J), (b) leads to the formation of the metal carbonyl derivatives LM(CO)5, L2M(CO)4 (M = Cr, Mo, W), LNi(CO)3 and LFe(CO)4 L = (CH3)2SbM(CO)3-π-C5H5] which are the first (CH3)2Sb-bridged polynuclear complexes. Phosphorus ylides cause heterolytic cleavage of the antimonytransition metal bond. Transfer of the (CH3)2Sb-group to the ylidic carbanion occurs via substitution/transylidation. All new compounds have been fully characterized by means of 1H NMR, IR and mass spectroscopy |
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