Organoborane Chemistry : by Thomas ONak,Academic Press,New York and London, 1975, x + 360 pages, $38, £18.25. |
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| Authors: | Donald S Matteson |
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| Institution: | Department of Chemistry Washington State University Pullman, Washington 99163 U.S.A. |
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| Abstract: | Methyl iodide reacts with Pt2(μ-SMe)2Ph2(PMe2Ph)2 to give PtIPh(SMe2)(PMe2Ph) and with Pt2(μ-SMe)2Me2(PMe2Ph)2 to give PtI2Me2(SMe2)(PMe2Ph) via an isolable intermediate Pt2I2(μ-SMe)2Me4(PMe2Ph)2. The mechanisms of the reactions are discussed. |
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