Some reactions of potassium perfluoro-t-butoxide with strong oxidizing agents |
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| Authors: | Nyal S Walker Darryl D Desmarteau |
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| Institution: | Department of Chemistry, Kansas State University, Manhattan, Kansas 66506 U.S.A. |
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| Abstract: | Several reactions of potassium perfluoro-t-butoxide with strong oxidizing agents have been studied. The new compounds (CF3)3COOSO2F and (CF3)3CONO2 have been prepared by reactions with peroxydisulfuryl difluoride and nitryl fluoride, and their properties are reported. Evidence is also presented for the formation of the novel peroxy salt KOOCF3 in the reaction with bis(fluoroxy)difluoromethane. A mechanism for the reaction of —OF compounds with KOC(CF3)3 is proposed. |
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