Adsorption of acetone on the mercury electrode from H2O+(CH3)2CO+HCl solutions |
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| Authors: | Zofia Borkowska |
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| Affiliation: | Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw (Poland) |
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| Abstract: | The adsorption of acetone on a mercury electrode from (CH3)2CO+H2O+HCl solutions has been studied using a thermodynamically rigorous procedure. The chemical potential of the supporting electrolyte has been kept constant by using the concentrations corresponding to the constant e.m.f. of the cell with electrodes reversible to each of the ions in the solutions. It is suggested that the molecule is to some extent oriented with the hydrocarbon part towards mercury. The composition of the surface layer has been calculated. |
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