New nitrosyl(perfluorocarboxylato) complexes of the platinum metals |
| |
| Authors: | Alan Dobson Stephen D. Robinson |
| |
| Affiliation: | Department of Chemistry, King''s College, Strand, London, WC2R 2LS Great Britain |
| |
| Abstract: | Perfluorocarboxylic acids (RFCOOH) (RF = CF3,C2F5 and (for Rh) C6F5) react with the species [M(NO)2(PPh3)2] (M = Ru, Os) and [M′(NO)(PPh3)3] (M′ = Rh, Ir) to yield new nitrosyl complexes [Ru(OCORF)3(NO)(PPh3)2], [OsH(OCORF)2(NO)(PPh3)2], [Os(OCORF)(NO)2(PPh3)2][OCORF], [Ir(OCORF)(NO)(PPh3)2][OCORF] and [Rh(OCORF)2(NO)(PPh3)2]. |
| |
| Keywords: | To whom correspondence should be addressed. |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
