New nitrosyl(perfluorocarboxylato) complexes of the platinum metals |
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| Authors: | Alan Dobson Stephen D Robinson |
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| Institution: | Department of Chemistry, King''s College, Strand, London, WC2R 2LS Great Britain |
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| Abstract: | Perfluorocarboxylic acids (RFCOOH) (RF = CF3,C2F5 and (for Rh) C6F5) react with the species M(NO)2(PPh3)2] (M = Ru, Os) and M′(NO)(PPh3)3] (M′ = Rh, Ir) to yield new nitrosyl complexes Ru(OCORF)3(NO)(PPh3)2], OsH(OCORF)2(NO)(PPh3)2], Os(OCORF)(NO)2(PPh3)2]OCORF], Ir(OCORF)(NO)(PPh3)2]OCORF] and Rh(OCORF)2(NO)(PPh3)2]. |
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| Keywords: | To whom correspondence should be addressed |
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