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Trilinear mode effects on transport coefficients
Authors:IA Michaels  I Oppenheim
Institution:Chemistry Department, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA
Abstract:The effects of tri-linear modes on transport coefficients is illustrated by explicit calculations for the self-diffusion constant. In two dimensions the form of the asymptotic time behavior of the velocity autocorrelation function is changed from t-1 (bilinear modes) to (t log t)-1 (trilinear modes). Thus, no finite mode calculation in two dimensions can yield the correct asymptotic form. A heuristic self-consistent calculation including all mode orders yields the form t log12 t]-1. In three dimensions, the form of the asymptotic time behavior is not changed when higher-order modes are included.
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