Metal Carbonyl Spectra : by P.S. Braterman,Academic Press,London/New York/San Francisco, 1975, vii + 286 pages, $22.25. |
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Authors: | Donald J Darensbourg |
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Institution: | Department of Chemistry, Tulane University, New Orleans, Louisiana 70118 U.S.A. |
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Abstract: | Vinyl halides react with alkyllithium compounds in the presence of tetrakis(triphenylphosphine)palladium to give olefins stereospecifically in excellent or fairly good yields. When less reactive Grignard reagents are employed instead of alkyllithium compounds, these reactions can be carried out catalytically with palladium. |
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