The effect of orientation of the lateral methyl substituent on the mesophase behaviour of 4-alkoxyphenylazo aryl benzoates |
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Authors: | Magdi M Naoum Abdelgawad A Fahmi Amira H Abaza Gamal R Saad |
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Institution: | 1. Chemistry Department, Faculty of Science, Cairo University, Giza, Egyptmagdinaoum@yahoo.co.uk;3. Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt |
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Abstract: | Two homologous series of 4-alkoxyphenylazo 4?-(2?- (and 3?-) methyl-) 4?-substituted benzoates (IIna–f and IIIna–f, six series each) were prepared and investigated. Within each series, the length of the terminal alkoxy group varies among 6, 8, 10 and 12 carbons, while the other terminal substituent, X, is a polar group that alternatively changes between the electron-donating CH3O, CH3, and the electron-withdrawing Br, NO2 and CN groups, in addition to the un-substituted analogue, X = H, aiming to investigate the effect of the different orientations of the methyl groups substituted on the central benzene ring, on the mesophase behaviour. The mesomorphic properties were discussed in terms of steric and polarisability effects. The mesophase stability was correlated with the polarisability anisotropy of bonds to the terminal substituent X. Comparative studies were made between the prepared isomers with each other and with the previously investigated laterally neat analogues 4-(4?-alkoxyphenylazo) phenyl 4?-substituted benzoates (Ina–f). |
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Keywords: | phenylazo phenyl benzoates mesophase behaviour lateral-methyl substitution polarisability |
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