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Synthesis of 4H-benz[de]anthracen-4-ones via 1,2-addition of metal acetylides to benzanthrone
Authors:Rui Umeda  Teruaki Namba  Yuji Shimizu
Institution:1. Faculty of Chemistry, Materials and Bioengineering, Kansai University, Osaka, Japanumeda@kansai-u.ac.jp;4. nishiya@kansai-u.ac.jp;5. Faculty of Chemistry, Materials and Bioengineering, Kansai University, Osaka, Japan
Abstract:Easy and facile syntheses of the 4H-benzde]anthracen-4-one derivatives were achieved by the reaction of benzanthrone and lithium acetylides, followed by the treatment with silica gel in CHCl3.
Keywords:Benzanthrone  4H-benz[de]anthracen-4-ones  metal acetylides
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