Synthesis of 4H-benz[de]anthracen-4-ones via 1,2-addition of metal acetylides to benzanthrone |
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Authors: | Rui Umeda Teruaki Namba Yuji Shimizu |
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Institution: | 1. Faculty of Chemistry, Materials and Bioengineering, Kansai University, Osaka, Japanumeda@kansai-u.ac.jp;4. nishiya@kansai-u.ac.jp;5. Faculty of Chemistry, Materials and Bioengineering, Kansai University, Osaka, Japan |
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Abstract: | Easy and facile syntheses of the 4H-benzde]anthracen-4-one derivatives were achieved by the reaction of benzanthrone and lithium acetylides, followed by the treatment with silica gel in CHCl3. |
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Keywords: | Benzanthrone 4H-benz[de]anthracen-4-ones metal acetylides |
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