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Chiral phosphine-phosphoramidite ligands in asymmetric catalysis
Authors:Xiu-Shuai Chen
Affiliation:1. School of Light Industry and Chemical Enginerring, Dalian Polytechnic University, Dalian, China;2. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China
Abstract:Chiral phosphine-phosphoramidite ligands, featuring ready availability, easy modification, and stability towards air and moisture, have recently emerged as a new kind of robust ligands for asymmetric catalysis. They have been found to display wide utilities in various catalytic asymmetric reactions, giving excellent enantioselectivities in the Rh-, Ru-, and Ir-catalyzed asymmetric hydrogenation of C?C, C?O, and C?N double bonds; Rh-catalyzed asymmetric hydroformylation; Pd-catalyzed asymmetric hydrophosphorylation; Pd-catalyzed asymmetric allylic alkylation; Ag-catalyzed asymmetric [3 + 2] cycloaddition; and Cu-catalyzed conjugate addition and reduction. In this review, the progress on the development of chiral phosphine-phosphoramidite ligands in asymmetric catalysis has been summarized.
Keywords:Asymmetric catalysis  chiral ligand  hydroformylation  hydrogenation  phosphine-phosphoramidite
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