Photo-responsive liquid crystalline elastomer with reduced chemically modified graphene oxide |
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Authors: | Renbo Wei Zicheng Wang Hongxing Zhang |
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Affiliation: | 1. Research Branch of Advanced Functional Materials, School of Microelectronics and Solid-State Electronics, High Temperature Resistant Polymer and Composites Key Laboratory of Sichuan Province, University of Electronic Science and Technology of China, Chengdu, P. R. Chinaweirb10@uestc.edu.cn;3. Research Branch of Advanced Functional Materials, School of Microelectronics and Solid-State Electronics, High Temperature Resistant Polymer and Composites Key Laboratory of Sichuan Province, University of Electronic Science and Technology of China, Chengdu, P. R. China |
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Abstract: | Photo-responsive liquid crystalline elastomer (LCE) with reduced chemically modified graphene oxide (RMGO) was fabricated and studied. Mesogenic groups modified graphene oxide (MGO) was prepared, reduced and characterised, then the obtained RMGO was mixed with an acrylate monomer containing a side-on mesogen, a crosslinker and a photoinitiator. After being oriented with magnetic field, well-defined LCE micropillar as photo-responsive actuators were fabricated from the mixture by the method combining soft lithography and photo-polymerisation/photo-crosslinking. The LCE micropillars showed reversible thermo-mechanical deformation during the nematic-to-isotropic transition temperature. Upon irradiating with red light (650 nm), photo-mechanical responses of the RMGO-containing LCE was demonstrated. This micron-sized LCE actuators can be used for remote photo-responsive devices. |
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Keywords: | Liquid crystal elastomer actuators photo-responsive reduced graphene oxide |
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