杯吡咯和杂杯吡咯的结构、合成与应用

杯吡咯以其特殊的结构和优异性能, 在主客体化学尤其是分子识别等方面的应用前景已备受关注, 合成新型功能化杯吡咯及其衍生物已成为超分子化学领域的研究热点之一. 近年来通过引入新型芳烃基体合成了结构和性能多样的杂杯吡咯. 主要介绍了功能化的杯吡咯和杂杯吡咯的结构、合成及其在分子识别等领域的应用.

Structure, Synthesis and Application of Calixpyrrole andHet-ero-calixpyrrole

The prospective application of calixpyrrole to the host-guest chemistry has received much attention, due to its special structure and excellent capability. Synthesis of new functionalized calixpyrrole and its derivatives has become one of the hot spots in the field of supramolecular chemistry. In recent years hetero-calixpyrroles with varial structures and remarkable host properties have been synthesized through introducing nonclassical building units into the calixpyrrole framework. This paper mainly introduces the structure, synthesis and application to molecular recognition by calixpyrrole and hetero-calixpyrrole.