Mixed-valent dodecanuclear vanadium cluster encapsulating chloride anions and its reaction to form a "bowl"-shaped cluster |
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| Authors: | Konar Sanjit Clearfield Abraham |
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| Affiliation: | Department of Chemistry, Texas A&M University, College Station, TX 77843, USA. skonar@mail.chem.tamu.edu |
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| Abstract: | Two oxovanadium phosphonate cage compounds have been synthesized in an organic solvent, and their characterization has been done by single-crystal X-ray analysis, IR spectroscopy, and bond valence sum calculations. The simple reaction of a mixed-valent closed V12 cage system produced another quasi-closed system composed of two V6 bowl-type cages. |
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