Dielectric Study of n-Butyl Acetate–Alcohol Mixtures by Time-Domain Reflectometry

Using picosecond time-domain reflectometry (TDR), dielectric relaxation studies have been carried out on binary mixtures of n-butyl acetate with methanol, ethanol, and 1-propanol, over the frequency range from 10 MHz to 20 GHz, at various concentrations and temperatures. The excess permittivity, excess inverse relaxation time, Kirkwood correlation factor, and thermodynamic parameters have been obtained. The excess permittivity for all the systems is negative. The values of static permittivity and relaxation time decrease with an increase in the percentage of n-butyl acetate in the mixtures.